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- W143751266 abstract "It is the objective of this project to isolate the asphaltene and preasphaltene fractions from coal liquids from a number of liquefaction processes. These processes consist of in general: catalytic hydrogenation, staged pyrolysis and solvent refining. The asphaltene fractions may be further separated by both gradient elution through column chromatography, and molecular size distribution through gel permeation chromatography. These coal-derived asphaltene and preashpaltene fractions will then be investigated by various chemical and physical methods for characterization of their structures. After the parameters are obtained, these parameters will be correlated with the refining and conversion variables which control a given type of liquefaction process. The effects of asphaltene in catalysis, ash or metal removal, desulfurization and denitrification will also be correlated. It is anticipated that understanding the role of asphaltenes in liquefaction processes will enable engineers to both improve existing processes, and to make recommendations for operational changes in planned liquefaction units. The objective of Phase 1 was to complete the isolation and separation of coal liquid fractions and to initiate their characterization. The objective of Phase 2 is to continue the characterization of coal asphaltenes and other coal liquid fractions by use of physical and instrumental methods. The structural parameters obtained will be used to postulate hypothetical average structures for coal liquid fractions.The objective of Phase 3 is to concentrate on the characterization of the preasphaltene (benzene insoluble fraction) of coal liquid fraction by the available physical and chemical methods to obtain a number of structural parameters." @default.
- W143751266 created "2016-06-24" @default.
- W143751266 creator A5077589077 @default.
- W143751266 date "1979-01-01" @default.
- W143751266 modified "2023-09-27" @default.
- W143751266 title "Chemistry and structure of coal derived asphaltenes and preasphaltenes. Interim report" @default.
- W143751266 doi "https://doi.org/10.2172/5721538" @default.
- W143751266 hasPublicationYear "1979" @default.
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