Matches in SemOpenAlex for { <https://semopenalex.org/work/W1437649069> ?p ?o ?g. }
- W1437649069 endingPage "98" @default.
- W1437649069 startingPage "90" @default.
- W1437649069 abstract "The local volume fractions of water, acetonitrile, and C18-bonded chains across the 96Åmesopores of 5μm Symmetry particles were determined semi-empirically. The semi-empirical approach was based on previous molecular dynamics studies, which provided relevant mathematical expressions for the density profiles of C18 chains and water molecules, and on minor disturbance experiments, which measured the excess amount of acetonitrile adsorbed in the pores of Symmetry-C18 particles. The pore walls of the Symmetry-C18 material were in thermodynamic equilibrium with a series of binary mixtures of water and acetonitrile. The results show that C18 chains are mostly solvated by acetonitrile molecules, water is excluded from the C18-bonded layer, and acetonitrile concentrates across a 15-25Åthick interface region between the C18 layer and the bulk phase. These actual density profiles are expected to have a direct impact on the retention behaviour of charged, polar, and neutral analytes in RPLC. They also provide clues to predict the local mobility of analytes inside the pores and a sound physico-chemical description of the phenomenon of surface diffusion observed in RPLC." @default.
- W1437649069 created "2016-06-24" @default.
- W1437649069 creator A5038183935 @default.
- W1437649069 date "2015-09-01" @default.
- W1437649069 modified "2023-10-16" @default.
- W1437649069 title "Determination of the solvent density profiles across mesopores of silica-C18 bonded phases in contact with acetonitrile/water mixtures: A semi-empirical approach" @default.
- W1437649069 cites W142879737 @default.
- W1437649069 cites W177999493 @default.
- W1437649069 cites W18455514 @default.
- W1437649069 cites W1968873408 @default.
- W1437649069 cites W1971429559 @default.
- W1437649069 cites W1972425020 @default.
- W1437649069 cites W1972942934 @default.
- W1437649069 cites W1974916290 @default.
- W1437649069 cites W1975107236 @default.
- W1437649069 cites W1978487711 @default.
- W1437649069 cites W1983084613 @default.
- W1437649069 cites W1984965695 @default.
- W1437649069 cites W1987791309 @default.
- W1437649069 cites W1989120447 @default.
- W1437649069 cites W1989897957 @default.
- W1437649069 cites W1990153852 @default.
- W1437649069 cites W1999327425 @default.
- W1437649069 cites W2005471568 @default.
- W1437649069 cites W2012887210 @default.
- W1437649069 cites W2029672236 @default.
- W1437649069 cites W2042799881 @default.
- W1437649069 cites W2043245115 @default.
- W1437649069 cites W2046497909 @default.
- W1437649069 cites W2046654815 @default.
- W1437649069 cites W2049263320 @default.
- W1437649069 cites W2052497762 @default.
- W1437649069 cites W2053592439 @default.
- W1437649069 cites W2054678000 @default.
- W1437649069 cites W2056739243 @default.
- W1437649069 cites W2065421967 @default.
- W1437649069 cites W2066496952 @default.
- W1437649069 cites W2069610606 @default.
- W1437649069 cites W2072741768 @default.
- W1437649069 cites W2075686295 @default.
- W1437649069 cites W2076676827 @default.
- W1437649069 cites W2077976850 @default.
- W1437649069 cites W2082448462 @default.
- W1437649069 cites W2085093758 @default.
- W1437649069 cites W2093938464 @default.
- W1437649069 cites W2111182545 @default.
- W1437649069 cites W2114781744 @default.
- W1437649069 cites W2140241696 @default.
- W1437649069 cites W2145070169 @default.
- W1437649069 cites W2184953350 @default.
- W1437649069 cites W2325745184 @default.
- W1437649069 cites W2329306961 @default.
- W1437649069 doi "https://doi.org/10.1016/j.chroma.2015.07.073" @default.
- W1437649069 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26255111" @default.
- W1437649069 hasPublicationYear "2015" @default.
- W1437649069 type Work @default.
- W1437649069 sameAs 1437649069 @default.
- W1437649069 citedByCount "22" @default.
- W1437649069 countsByYear W14376490692015 @default.
- W1437649069 countsByYear W14376490692016 @default.
- W1437649069 countsByYear W14376490692017 @default.
- W1437649069 countsByYear W14376490692018 @default.
- W1437649069 countsByYear W14376490692019 @default.
- W1437649069 countsByYear W14376490692020 @default.
- W1437649069 countsByYear W14376490692021 @default.
- W1437649069 countsByYear W14376490692022 @default.
- W1437649069 countsByYear W14376490692023 @default.
- W1437649069 crossrefType "journal-article" @default.
- W1437649069 hasAuthorship W1437649069A5038183935 @default.
- W1437649069 hasConcept C113196181 @default.
- W1437649069 hasConcept C121332964 @default.
- W1437649069 hasConcept C1276947 @default.
- W1437649069 hasConcept C150394285 @default.
- W1437649069 hasConcept C159467904 @default.
- W1437649069 hasConcept C161790260 @default.
- W1437649069 hasConcept C178790620 @default.
- W1437649069 hasConcept C185592680 @default.
- W1437649069 hasConcept C2777463227 @default.
- W1437649069 hasConcept C2780471494 @default.
- W1437649069 hasConcept C29705727 @default.
- W1437649069 hasConcept C32909587 @default.
- W1437649069 hasConcept C43617362 @default.
- W1437649069 hasConcept C69357855 @default.
- W1437649069 hasConcept C82776694 @default.
- W1437649069 hasConcept C97355855 @default.
- W1437649069 hasConceptScore W1437649069C113196181 @default.
- W1437649069 hasConceptScore W1437649069C121332964 @default.
- W1437649069 hasConceptScore W1437649069C1276947 @default.
- W1437649069 hasConceptScore W1437649069C150394285 @default.
- W1437649069 hasConceptScore W1437649069C159467904 @default.
- W1437649069 hasConceptScore W1437649069C161790260 @default.
- W1437649069 hasConceptScore W1437649069C178790620 @default.
- W1437649069 hasConceptScore W1437649069C185592680 @default.
- W1437649069 hasConceptScore W1437649069C2777463227 @default.
- W1437649069 hasConceptScore W1437649069C2780471494 @default.
- W1437649069 hasConceptScore W1437649069C29705727 @default.
- W1437649069 hasConceptScore W1437649069C32909587 @default.
- W1437649069 hasConceptScore W1437649069C43617362 @default.