Matches in SemOpenAlex for { <https://semopenalex.org/work/W1440615756> ?p ?o ?g. }
- W1440615756 endingPage "407" @default.
- W1440615756 startingPage "377" @default.
- W1440615756 abstract "This chapter discusses structural evolution of silver and gold clusters. A series of unique structural transitions in gold anion clusters throughout the size range of n=11–24 atoms is observed. The identification of these are accomplished through direct structural determination – that is, the comparison of electron diffraction data from trapped clusters with density functional calculations of structural isomers for each cluster size. These transitions exhibit changes in form and symmetry evolving from planar species at n=11 to hollow cages, and finally to a highly symmetric, tube-like structure at n = 24 observed in these diffraction measurements for the first time. The rich array of size-dependent structural motifs described in this study is specific to gold clusters, and it is likely to originate from the relativistically enhanced s–d hybridization of gold bonding orbitals. The determination of these cluster structures, achieved through joint electron diffraction measurements and first principles calculations, adds to the published plethora of gold structures. Most importantly, the determination of these cluster structures is essential to an understanding of the size-dependent evolution of cluster properties, for example, assisting a more complete understanding of the mechanisms that control the chemical reactivity and catalytic activity of gold clusters." @default.
- W1440615756 created "2016-06-24" @default.
- W1440615756 creator A5055048772 @default.
- W1440615756 creator A5071115545 @default.
- W1440615756 date "2007-01-01" @default.
- W1440615756 modified "2023-10-16" @default.
- W1440615756 title "Chapter 9 Trapped ion electron diffraction: structural evolution of silver and gold clusters" @default.
- W1440615756 cites W1513428341 @default.
- W1440615756 cites W196092285 @default.
- W1440615756 cites W1963837576 @default.
- W1440615756 cites W1965237119 @default.
- W1440615756 cites W1966432511 @default.
- W1440615756 cites W1966787111 @default.
- W1440615756 cites W1968008526 @default.
- W1440615756 cites W1970600786 @default.
- W1440615756 cites W1970885336 @default.
- W1440615756 cites W1971481652 @default.
- W1440615756 cites W1971840671 @default.
- W1440615756 cites W1973769167 @default.
- W1440615756 cites W1977372139 @default.
- W1440615756 cites W1981368803 @default.
- W1440615756 cites W1984191478 @default.
- W1440615756 cites W1989301456 @default.
- W1440615756 cites W1989638631 @default.
- W1440615756 cites W1993149608 @default.
- W1440615756 cites W1997472565 @default.
- W1440615756 cites W2001521319 @default.
- W1440615756 cites W2002810826 @default.
- W1440615756 cites W2003249955 @default.
- W1440615756 cites W2007941201 @default.
- W1440615756 cites W2009637681 @default.
- W1440615756 cites W2010248660 @default.
- W1440615756 cites W2010560396 @default.
- W1440615756 cites W2015884059 @default.
- W1440615756 cites W2016936301 @default.
- W1440615756 cites W2020865414 @default.
- W1440615756 cites W2021898523 @default.
- W1440615756 cites W2023492791 @default.
- W1440615756 cites W2028228833 @default.
- W1440615756 cites W2033830521 @default.
- W1440615756 cites W2034530880 @default.
- W1440615756 cites W2036391022 @default.
- W1440615756 cites W2041767218 @default.
- W1440615756 cites W2043031247 @default.
- W1440615756 cites W2044768445 @default.
- W1440615756 cites W2045596260 @default.
- W1440615756 cites W2050873114 @default.
- W1440615756 cites W2051067248 @default.
- W1440615756 cites W2058865216 @default.
- W1440615756 cites W2059527620 @default.
- W1440615756 cites W2063122139 @default.
- W1440615756 cites W2068241704 @default.
- W1440615756 cites W2070696605 @default.
- W1440615756 cites W2074998400 @default.
- W1440615756 cites W2077174397 @default.
- W1440615756 cites W2077386703 @default.
- W1440615756 cites W2081209556 @default.
- W1440615756 cites W2086027263 @default.
- W1440615756 cites W2092204065 @default.
- W1440615756 cites W2094199050 @default.
- W1440615756 cites W2113998630 @default.
- W1440615756 cites W2116720872 @default.
- W1440615756 cites W2129360151 @default.
- W1440615756 cites W2138317675 @default.
- W1440615756 cites W2138609803 @default.
- W1440615756 cites W2142385989 @default.
- W1440615756 cites W2151078545 @default.
- W1440615756 cites W4235610199 @default.
- W1440615756 doi "https://doi.org/10.1016/s1571-0785(07)12009-5" @default.
- W1440615756 hasPublicationYear "2007" @default.
- W1440615756 type Work @default.
- W1440615756 sameAs 1440615756 @default.
- W1440615756 citedByCount "3" @default.
- W1440615756 countsByYear W14406157562014 @default.
- W1440615756 countsByYear W14406157562020 @default.
- W1440615756 countsByYear W14406157562021 @default.
- W1440615756 crossrefType "book-chapter" @default.
- W1440615756 hasAuthorship W1440615756A5055048772 @default.
- W1440615756 hasAuthorship W1440615756A5071115545 @default.
- W1440615756 hasConcept C120665830 @default.
- W1440615756 hasConcept C121332964 @default.
- W1440615756 hasConcept C145148216 @default.
- W1440615756 hasConcept C147120987 @default.
- W1440615756 hasConcept C147597530 @default.
- W1440615756 hasConcept C152365726 @default.
- W1440615756 hasConcept C159467904 @default.
- W1440615756 hasConcept C164866538 @default.
- W1440615756 hasConcept C178790620 @default.
- W1440615756 hasConcept C185592680 @default.
- W1440615756 hasConcept C192562407 @default.
- W1440615756 hasConcept C199360897 @default.
- W1440615756 hasConcept C207114421 @default.
- W1440615756 hasConcept C2779175510 @default.
- W1440615756 hasConcept C2780740876 @default.
- W1440615756 hasConcept C41008148 @default.
- W1440615756 hasConcept C62520636 @default.
- W1440615756 hasConcept C77557913 @default.
- W1440615756 hasConcept C8010536 @default.