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- W1443316292 abstract "UV-Visible Reflection-Absorption Spectroscopy (UVRAS) technique is reviewed with a general perspective on fundamental and applications. UVRAS is formally identical to IR Reflection-Absorption Spectroscopy (IRRAS), and therefore, the methodology developed for this IR technique can be applied in the UV-visible region. UVRAS can be applied to air-solid, air-liquid or liquid-liquid interfaces. This review focuses on the use of UVRAS for studying Langmuir monolayers. We introduce the theoretical framework for a successful understanding of the UVRAS data, and we illustrate the usage of this data treatment to a previous study from our group comprising an amphiphilic porphyrin. For ultrathin films with a thickness of few nm, UVRAS produces positive or negative bands when p-polarized radiation is used, depending on the incidence angle and the orientation of dipole absorption. UVRAS technique provides highly valuable information on tilt of chromophores at the air-liquid interface, and moreover allows the determination of optical parameters. We propose UVRAS as a powerful technique to investigate the in situ optical properties of Langmuir monolayers." @default.
- W1443316292 created "2016-06-24" @default.
- W1443316292 creator A5019118546 @default.
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- W1443316292 creator A5045097519 @default.
- W1443316292 creator A5050487254 @default.
- W1443316292 creator A5063451477 @default.
- W1443316292 date "2015-11-01" @default.
- W1443316292 modified "2023-10-18" @default.
- W1443316292 title "UV–Vis Reflection–Absorption Spectroscopy at air–liquid interfaces" @default.
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