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- W1444106567 abstract "This chapter discusses the significant recent advances in oxazolone chemistry. Five different structures can be written for the oxazolones—namely, 5(4H)-oxazolone, 5(2H)-oxazolone, 4(5H)-oxazolone, 2(3H)-oxazolone, and 2(5H)-oxazolone. The methods of preparation of 2-oxazolin-5-ones [5(4H)-Oxazolone], the reactions related to it, and its stereochemistry are also reviewed in the chapter. The behavior of unsaturated azlactones with organometallic reagents has been described in the chapter. The 4-unsaturated-5-oxazolones provide convenient starting materials for the synthesis of several nitrogen-containing heterocyclic systems. The chapter also discusses the preparation of tetrazoles and isoquinolines and the isolation of several pairs of the geometric isomers of 4-unsaturated-5-oxazolones. The chemical properties of the pseudooxazolones depend to some extent on the type of substitution at the 2-position of the hetero ring; it is divided into two parts—(1) 2-arylidenepseudooxazolones and (2) 2-trifluoromethylpseudooxazolones." @default.
- W1444106567 created "2016-06-24" @default.
- W1444106567 creator A5079619470 @default.
- W1444106567 date "1965-01-01" @default.
- W1444106567 modified "2023-10-16" @default.
- W1444106567 title "Recent Advances in Oxazolone Chemistry" @default.
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- W1444106567 doi "https://doi.org/10.1016/s0065-2725(08)60875-2" @default.
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