Matches in SemOpenAlex for { <https://semopenalex.org/work/W1445542169> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W1445542169 endingPage "360" @default.
- W1445542169 startingPage "350" @default.
- W1445542169 abstract "This chapter discusses the temperature-difference spectra of flavins and flavoproteins. The difference spectra discussed in this chapter results from an unperturbed (reference cell) and a temperature-perturbed (sample cell) spectrum. The perturbation of the chromophore results in a red or blue shift of the absorption bands along the wavelength axis, and it can also cause a decrease or increase in the intensity of the absorption. If the absorption bands could be considered as homogeneous curves, then the difference between the two spectra would resemble the first derivatives of the curves. The two lowest electronic transitions in flavin spectra are not homogeneous, as they consist of several vibronic bands. The resolution of the vibronic bands depends strongly on the environment of the flavin and the observed temperature-difference band of a particular electronic transition is, therefore, complex. The temperature-difference spectra of the flavoproteins that have been investigated show isosbestic points where the spectra cross the base line. These points indicate that the flavin has not dissociated from the protein during the experiment; where such dissociation occurs, the difference spectra are no longer isosbestic and the changes often become partly irreversible so that the original base line is not obtained when the sample is subsequently cooled to the temperature of the reference cuvette." @default.
- W1445542169 created "2016-06-24" @default.
- W1445542169 creator A5002630852 @default.
- W1445542169 creator A5063757553 @default.
- W1445542169 date "1980-01-01" @default.
- W1445542169 modified "2023-09-27" @default.
- W1445542169 title "[50] Temperature-difference spectra of flavins and flavoproteins" @default.
- W1445542169 cites W1497254911 @default.
- W1445542169 cites W1573597811 @default.
- W1445542169 cites W1964427499 @default.
- W1445542169 cites W1983786494 @default.
- W1445542169 cites W1991535128 @default.
- W1445542169 cites W2055327093 @default.
- W1445542169 doi "https://doi.org/10.1016/0076-6879(80)66480-5" @default.
- W1445542169 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/7374478" @default.
- W1445542169 hasPublicationYear "1980" @default.
- W1445542169 type Work @default.
- W1445542169 sameAs 1445542169 @default.
- W1445542169 citedByCount "3" @default.
- W1445542169 crossrefType "book-chapter" @default.
- W1445542169 hasAuthorship W1445542169A5002630852 @default.
- W1445542169 hasAuthorship W1445542169A5063757553 @default.
- W1445542169 hasConcept C113196181 @default.
- W1445542169 hasConcept C119824511 @default.
- W1445542169 hasConcept C120665830 @default.
- W1445542169 hasConcept C121332964 @default.
- W1445542169 hasConcept C1276947 @default.
- W1445542169 hasConcept C181199279 @default.
- W1445542169 hasConcept C185592680 @default.
- W1445542169 hasConcept C192468462 @default.
- W1445542169 hasConcept C33093398 @default.
- W1445542169 hasConcept C43617362 @default.
- W1445542169 hasConcept C4839761 @default.
- W1445542169 hasConcept C55493867 @default.
- W1445542169 hasConcept C71995715 @default.
- W1445542169 hasConcept C75473681 @default.
- W1445542169 hasConceptScore W1445542169C113196181 @default.
- W1445542169 hasConceptScore W1445542169C119824511 @default.
- W1445542169 hasConceptScore W1445542169C120665830 @default.
- W1445542169 hasConceptScore W1445542169C121332964 @default.
- W1445542169 hasConceptScore W1445542169C1276947 @default.
- W1445542169 hasConceptScore W1445542169C181199279 @default.
- W1445542169 hasConceptScore W1445542169C185592680 @default.
- W1445542169 hasConceptScore W1445542169C192468462 @default.
- W1445542169 hasConceptScore W1445542169C33093398 @default.
- W1445542169 hasConceptScore W1445542169C43617362 @default.
- W1445542169 hasConceptScore W1445542169C4839761 @default.
- W1445542169 hasConceptScore W1445542169C55493867 @default.
- W1445542169 hasConceptScore W1445542169C71995715 @default.
- W1445542169 hasConceptScore W1445542169C75473681 @default.
- W1445542169 hasLocation W14455421691 @default.
- W1445542169 hasLocation W14455421692 @default.
- W1445542169 hasOpenAccess W1445542169 @default.
- W1445542169 hasPrimaryLocation W14455421691 @default.
- W1445542169 hasRelatedWork W1445542169 @default.
- W1445542169 hasRelatedWork W1522769968 @default.
- W1445542169 hasRelatedWork W2023347568 @default.
- W1445542169 hasRelatedWork W2042850764 @default.
- W1445542169 hasRelatedWork W2063864843 @default.
- W1445542169 hasRelatedWork W2090505184 @default.
- W1445542169 hasRelatedWork W2093088311 @default.
- W1445542169 hasRelatedWork W2211633146 @default.
- W1445542169 hasRelatedWork W2995147355 @default.
- W1445542169 hasRelatedWork W4207038040 @default.
- W1445542169 isParatext "false" @default.
- W1445542169 isRetracted "false" @default.
- W1445542169 magId "1445542169" @default.
- W1445542169 workType "book-chapter" @default.