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- W144601812 abstract "Moment analysis of the effluent peaks from input pulses to a packed column was used to study the activated adsorption of NO on Fe/sub 2/O/sub 3/ (14.2 percent Fe/sub 2/O/sub 3/ on Al/sub 2/O/sub 3/) at 370 to 410/sup 0/C. The adsorption equilibrium constant at 400/sup 0/C was 3.2 cm/sup 3//g and the heat of adsorption in the temperature range 370 to 410/sup 0/C was 12 kcal/mole. The adsorption equilibrium constant of NO decreased with time during flow of helium through the bed of particles. By auxiliary experiments with N/sub 2/O pulses it was confirmed that this decrease was due to desorption of atomically adsorbed oxygen. The combination of NO and N/sub 2/O pulse data provided evidence that NO was adsorbed on sites involving the adsorbed oxygen. Kinetic analysis of the data for the decrease in NO adsorption with time of helium flow suggested that the desorption of atomic oxygen was a second-order process with an activation energy of about 47 kcal/mole." @default.
- W144601812 created "2016-06-24" @default.
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- W144601812 date "1976-03-01" @default.
- W144601812 modified "2023-09-23" @default.
- W144601812 title "Pulse studies of the adsorption of nitric oxide on iron oxide surfaces. [370 to 410/sup 0/C]" @default.
- W144601812 hasPublicationYear "1976" @default.
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