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- W1449299174 abstract "Electrochemical behavior of pure zinc was studied in alkaline KOH-based media over a large range of voltage (0–300 V) in order to investigate the occurrence of the micro-arc phenomenon, responsible for the formation of “ceramic-like” oxide layer. According to electrolyte composition, three anodizing steps can be observed, first, a classical anodizing process at low voltage, a voltage range of micro-arc phenomenon with a more or less intense water oxidation, and a sharp current rise corresponding to an increase of electronic conductivity of “metal/oxide/electrolyte” interface. Both KOH concentration and presence of additives in the electrolytic bath control the micro-arc voltage range, and the composition of anodized layer. Nevertheless, the internal layer of the coating remains mainly constituted by crystallized ZnO, formed by a mechanism of solid-state diffusion of O2 − under electric field. Despite the significant coating thickness (several microns), the electrochemical characterization of the corrosion behavior in NaCl electrolyte only shows a slight improvement of the performances of the zinc anodized in presence of additives in KOH electrolyte, compared to an untreated one." @default.
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- W1449299174 date "2015-10-01" @default.
- W1449299174 modified "2023-10-06" @default.
- W1449299174 title "Electrochemical behavior of zinc in KOH media at high voltage: Micro-arc oxidation of zinc" @default.
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- W1449299174 doi "https://doi.org/10.1016/j.jelechem.2015.06.021" @default.
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