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- W144951664 abstract "A mechanism is proposed for producing nonequilibrium distributions of molecules over the rotational levels of the electronic-vibrational ground state in low-pressure plasmas that involves purely rotational excitation of molecules by electron impact. Only intermolecular and electron--molecule collisions are included in the balance equation for excitation and deexcitation of the rotational levels in the electronic-vibrational ground state /sup 1/..sigma.., V = 0. An adiabatic approximation is used to relate the rate constants for arbitrary rotational transitions to the rate constants for rotational excitation from the rotational ground state. The deviation from adiabatic conditions in intermolecular collisions is taken into account by introducing an additional exponential factor. It is assumed that transitions between adjacent rotational levels are dominant. Some simple recurrence relations are derived and analyzed for the populations of the rotational levels. These relations link the form of the rotational distribution to the rates of elementary processes and to the plasma parameters, including the degree of ionization, the mean electron energy and the gas temperature." @default.
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- W144951664 date "1980-10-01" @default.
- W144951664 modified "2023-09-24" @default.
- W144951664 title "Mechanism for production of nonequilibrium rotational level populations of molecules in plasmas. I. Theoretical model" @default.
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