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- W1463844077 abstract "Various kinds of metal oxides were tested as catalysts for vapor-phase oxidation of α-methylstyrene to form α-phenylacrolein (atropoaldehyde). The best performance was obtained with the Mo/ W/Te atomic ratio of 10/4/4 catalyst; one-pass yield of α-phenylacrolein attained 59 mol% at α-methylstyrene conversion of 91%. The rate of reaction increased proportionally to the oxygen concentration, while it was almost insensitive to the concentrations of α-methylstyrene and water vapor. Studies of reaction variables showed that an optimal yield of α-phenylacrolein is obtained under the conditions of long contact times, low temperatures, high oxygen concentrations, α-methylstyrene concentration of 1 to 2.4 mol%, and absence of water vapor. The results are discussed in the light of both the acid-base property and the oxidizing function of the metal oxides." @default.
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- W1463844077 date "1989-11-01" @default.
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- W1463844077 title "Oxidation of $alpha;-methylstyrene to phenylacrolein on MoO3$z.sbnd;WO3$z.sbnd;TeO2 catalysts" @default.
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- W1463844077 doi "https://doi.org/10.1016/0021-9517(89)90261-3" @default.
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