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- W146548962 abstract "A novel theory of droplet microemulsions is presented that is based on surface and small systems thermodynamics, and is formulated in terms of a large set of chemical complex equilibria which account for the size, shape and composition fluctuations. The fluctuation-caused polydispersity is shown to be of a rather limited relative magnitude but, nevertheless, it is of paramount importance when calculating the total volume fraction of microemulsion droplets. In the Winsor iI (w/o) two phase regime the fluctuations take place about an equilibrium droplet for which the Laplace pressure 2γ/R is exactly counterbalanced by the curvature pressure π c = −(∂γ/∂R)state. Hence, a sufficiently large curvature dependence on the interfacial tension γ is crucial for attaining thermodynamically stable droplet microemulsions." @default.
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- W146548962 date "2007-12-12" @default.
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- W146548962 title "The multiple chemical equilibrium approach to the theory of droplet microemulsions" @default.
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- W146548962 doi "https://doi.org/10.1007/bfb0115521" @default.
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