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- W1467178557 abstract "Publisher Summary There is a rapidly growing tendency among organic chemists for reactions of the type formerly called stereospecific to be called stereoselective. Although this usage does not represent a fixed state of affairs, the common inorganic usage has been revised, whereby stereospecificity refers to one molecular diastereoisomer having different properties from another, and call such effects stereoselective, in accordance with modern organic practice. It has been recognized for many years that, in the complexes of transition metals with optically active diamines, there are marked stereoselective effects. The earliest demonstrations of this matter rested on the isolation from reaction mixtures of less diastereoisomers than the predicted number. Very little work has been done on stereospecific effects in complexes of ligands other than diamines or amino acids. The possible effects in complexes of such ligands as amino-alcohols or diols have been overlooked.However, some data are available on complexes of (+) hydroxymethylenecamphor, which acts as a β-diketone. It is true that an apparently stereospecific reaction occurs with cobalt (III). From chromatographic work, it is clear that one diastereoisomer is present as ca. 95% of the mixture, so that the formation of tris (+) hydroxymethylenecamphoratocobalt (III) occurs with very marked stereoselectivity." @default.
- W1467178557 created "2016-06-24" @default.
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- W1467178557 date "1966-01-01" @default.
- W1467178557 modified "2023-09-26" @default.
- W1467178557 title "Stereoselectivity in Coordination Compounds" @default.
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- W1467178557 doi "https://doi.org/10.1016/s0065-2792(08)60304-0" @default.
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