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- W1469761764 abstract "The understanding the importance of realistic boundary conditions has been greatly enhanced by theoretical treatments of space charge and electrode polarization. One of the simplifications used to reduce the difficulties with solving the pertinent continuity equations is the neglect of the equilibrium space charge, which may be present at the crystal/electrode interface. The interest of the study in this chapter lies in the evidence that, such simplification may be rather crude and it reports the first attempt to measure anomalies of the lattice parameter near the surface of NaCI and KCl crystals. The lattice parameter measurements showed some scatter in different points of the crystals, comparable with the differences between the bulk and surface values in NaCl but well below the differences in KCI. The anomaly of lattice constant was smaller below the carbon covered surface than below the free surface, indicating that the presence of the conducting layer makes it easier to the crystal to attain a state close to equilibrium. The chapter summarizes the result showing an unexpected opposite sign of lattice deformation near the surface of NaCl and KCl crystals." @default.
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- W1469761764 date "1988-01-01" @default.
- W1469761764 modified "2023-10-18" @default.
- W1469761764 title "Lattice Deforimation Near the Surface of Some Ionic Crystals" @default.
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- W1469761764 doi "https://doi.org/10.1016/s0167-2991(08)65075-2" @default.
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