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- W1470529583 abstract "This chapter discusses the application of radiation techniques to study organic radicals. The primary radiation chemical processes are better understood in aqueous solutions than in any other system and they can be better controlled and utilized. The chapter deals with the reactions of organic compounds with transients from water, their rate constants and mechanisms, and their utilization for the production of organic radicals. The properties or organic radicals, their absorption spectra, their dissociation constants and various protonation processes, any structural rearrangements they undergo, and their reactivity towards each other and towards organic compounds are discussed. Several new developments in the analytical procedures, both in the determination of final products and in the direct observation of transient species are discussed. The primary effect of radiation on aqueous solution is the decomposition of the water, followed by reactions of the transients from water with the solutes present. Direct effect of radiation on the solute is practically negligible up to concentrations of about 1 M." @default.
- W1470529583 created "2016-06-24" @default.
- W1470529583 creator A5064613304 @default.
- W1470529583 date "1976-01-01" @default.
- W1470529583 modified "2023-09-26" @default.
- W1470529583 title "Application of Radiation Techniques to the Study of Organic Radicals" @default.
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