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- W147175053 abstract "Hydrophosphorylation of functionally substituted alkynes by phosphonic acids can be a convenient method for synthesis of functionally substituted mono- and diphosphine oxides. The ease of hydrophosphorylation is determined by the strength of the negative inductive effect of the substituents on the triple bond and the steric factor. The structure of the bis-adducts was confirmed by elementary analysis and the /sup 31/P and /sup 13/C NMR spectra. The /sup 31/P NMR spectrum is an AB two-spin system. The values of the chemical shifts and spin-spin interaction constants /sup 3/J/sub PP/ are in agreement with the data in the literature for similar compounds." @default.
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- W147175053 date "1987-08-20" @default.
- W147175053 modified "2023-09-26" @default.
- W147175053 title "Hydrophosphorylation of substituted alkynes by phosphonic acids" @default.
- W147175053 hasPublicationYear "1987" @default.
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