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- W14718260 abstract "The oxidation of secondary alcohols to ketones by air has been studied in aqueous alkaline solutions, in the presence of dodecylbenzenesulfonic acid Na salt detergent. The self-poisoning of a 5 wt% Pdalumina catalyst could be suppressed by Bi deposition onto the Pt particles. The origin of catalyst deactivation (self-poisoning or over-oxidation) was investigated by measuring the potential of the catalyst slurry during the oxidation reaction. It is suggested that the over-oxidation of Pt is the result, not the reason of catalyst deactivation. The reliability of the potential measurement in the presence of a non-conductive support is discussed. The catalyst potential was found to provide useful information for controlling the rate of oxygen supply, which helps to avoid the over-oxidation of the active sites. After optimization of the economically and environmentally important variables, 97-99 % conversion and 95-100 % selectivity could be achieved in the oxidation of water-insoluble alcohols." @default.
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- W14718260 date "1993-01-01" @default.
- W14718260 modified "2023-10-12" @default.
- W14718260 title "Partial oxidation of water—insoluble alcohols over Bi—promoted Pt on alumina. Electrochemical characterization of the catalyst in its working state" @default.
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- W14718260 doi "https://doi.org/10.1016/s0167-2991(08)63343-1" @default.
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