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- W1473611970 abstract "Knowledge of the kinetics and mechanism of BaMgAl210O17:Eu+(BAM) fusion with sodium hydroxide will benefit recycling rare earth elements(REEs) from the waste phosphors. The reaction temperature range of 290–375 ℃ and the reaction mechanism were determined using X-ray diffraction, scanning electron microscopy and differential scanning calorimetry. Activation energy was determined by the four model-free methods, and calculated results showed that the Kissinger method value of 579.5 KJ/mol was close to the average value of the Kissinger-Akahira-Sunose(KAS) and the Flynn-Wall-Ozawa(FWO) methods of 563.5 kJ /mol. The calculated activation energy variation tendency versus conversion factor agreed with the proposed mechanism." @default.
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- W1473611970 date "2015-01-01" @default.
- W1473611970 modified "2023-09-28" @default.
- W1473611970 title "Mechanism and kinetics of the BaMgAltoO17：Eu2＋ alkaline fusion reaction" @default.
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