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- W1475338077 abstract "In title compound, [Sn(C6H5)3(C9H6BrN2OS2)], the Sn atom is five-coordinated and the 1,3,4-thiadiazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate SnIV atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a distorted cis-trigonal bipyramidal geometry with the S atom and two C atoms occupying the equatorial plane, whereas the N atom and another C atom are in axial positions. In addition, there is a weak intramolecular Sn⋯N interaction. The crystal structure involves weak intramolecular C—H⋯N and intermolecular C—H⋯Br hydrogen bonding." @default.
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- W1475338077 date "2009-04-18" @default.
- W1475338077 modified "2023-09-24" @default.
- W1475338077 title "[5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV)" @default.
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- W1475338077 doi "https://doi.org/10.1107/s1600536809012793" @default.
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