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- W1475492871 abstract "Abstract New, simple and inexpensive receptors based on coumarin-thiocarbohydrazone (CTC) and coumarin-carbohydrazone (CC) were synthesized for fluoride ion in CH 3 CN/DMSO. Receptor CTC showed specific selectivity and sensitivity toward fluoride giving rise to an ON 1 –OFF–ON 2 fluorescent response and visual colorimetric change. The recognition mechanism was investigated using UV–vis, fluorescence spectroscopy, and 1 H NMR titration experiments. The Job's plot analysis and Benesi–Hildebrand equation revealed that the binding between the CTC or CC with F − is in 1:1 stoichiometry. Formation of such 1:1 complex led to the quenching of green fluorescence of CTC and upon excess addition of F − , the [CTC–F − ] complex underwent an intracomplex proton transfer from N H fragment of the host (CTC) to the anion producing a distinctly emissive (cyan colored fluorescence) receptor [CTC] 2− ." @default.
- W1475492871 created "2016-06-24" @default.
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- W1475492871 date "2016-01-01" @default.
- W1475492871 modified "2023-10-11" @default.
- W1475492871 title "Simple and efficient coumarin-based colorimetric and fluorescent chemosensor for F− detection: An ON1–OFF–ON2 fluorescent assay" @default.
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- W1475492871 doi "https://doi.org/10.1016/j.snb.2015.08.090" @default.
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