Matches in SemOpenAlex for { <https://semopenalex.org/work/W147809265> ?p ?o ?g. }
- W147809265 endingPage "228" @default.
- W147809265 startingPage "207" @default.
- W147809265 abstract "Monolithic chromatographic support structures offer, as compared to the conventional particulate materials, a unique combination of high bed permeability, optimized solute transport to and from the active surface sites and a high loading capacity by the introduction of hierarchical order in the interconnected pore network and the possibility to independently manipulate the contributing sets of pores. While basic principles governing flow resistance, axial dispersion and adsorption capacity are remaining identical, and a similarity to particulate systems can be well recognized on that basis, a direct comparison of sphere geometry with monolithic structures is less obvious due, not least, to the complex shape of theskeleton domain. We present here a simple, widely applicable, phenomenological approach for treating single-phase incompressible flow through structures having a continuous, rigid solid phase. It relies on the determination of equivalent particle (sphere) dimensions which characterize the corresponding behaviour in a particulate, i.e. discontinuous bed. Equivalence is then obtained by dimensionless scaling of macroscopic fluid dynamical behaviour, hydraulic permeability and hydrodynamic dispersion in both types of materials, without needing a direct geometrical translation of their constituent units. Differences in adsorption capacity between particulate and monolithic stationary phases show that the silica-based monoliths with a bimodal pore size distribution provide, due to the high total porosity of the material of more than 90%, comparable maximum loading capacities with respect to random-close packings of completely porous spheres." @default.
- W147809265 created "2016-06-24" @default.
- W147809265 creator A5062575590 @default.
- W147809265 creator A5086157711 @default.
- W147809265 date "2003-07-01" @default.
- W147809265 modified "2023-10-17" @default.
- W147809265 title "Chromatographic performance of monolithic and particulate stationary phases" @default.
- W147809265 cites W15494983 @default.
- W147809265 cites W1566855457 @default.
- W147809265 cites W1964885053 @default.
- W147809265 cites W1966961931 @default.
- W147809265 cites W1969427704 @default.
- W147809265 cites W1970115260 @default.
- W147809265 cites W1979431647 @default.
- W147809265 cites W1990245659 @default.
- W147809265 cites W1992962827 @default.
- W147809265 cites W1994096439 @default.
- W147809265 cites W1997388726 @default.
- W147809265 cites W1997829807 @default.
- W147809265 cites W1998719559 @default.
- W147809265 cites W1999810562 @default.
- W147809265 cites W2001195021 @default.
- W147809265 cites W2004468523 @default.
- W147809265 cites W2006966253 @default.
- W147809265 cites W2007734333 @default.
- W147809265 cites W2009232111 @default.
- W147809265 cites W2009283704 @default.
- W147809265 cites W2010363999 @default.
- W147809265 cites W2013400605 @default.
- W147809265 cites W2014661271 @default.
- W147809265 cites W2019145893 @default.
- W147809265 cites W2020796727 @default.
- W147809265 cites W2021324475 @default.
- W147809265 cites W2021800972 @default.
- W147809265 cites W2027209792 @default.
- W147809265 cites W2027876160 @default.
- W147809265 cites W2028335230 @default.
- W147809265 cites W2028421676 @default.
- W147809265 cites W2037179547 @default.
- W147809265 cites W2039815518 @default.
- W147809265 cites W2040152738 @default.
- W147809265 cites W2041303067 @default.
- W147809265 cites W2043965813 @default.
- W147809265 cites W2046348586 @default.
- W147809265 cites W2046892424 @default.
- W147809265 cites W2046978744 @default.
- W147809265 cites W2047238326 @default.
- W147809265 cites W2050353916 @default.
- W147809265 cites W2050682768 @default.
- W147809265 cites W2051032810 @default.
- W147809265 cites W2058420615 @default.
- W147809265 cites W2058507224 @default.
- W147809265 cites W2060518285 @default.
- W147809265 cites W2069935731 @default.
- W147809265 cites W2070457128 @default.
- W147809265 cites W2071172293 @default.
- W147809265 cites W2074545779 @default.
- W147809265 cites W2075526454 @default.
- W147809265 cites W2075845931 @default.
- W147809265 cites W2079393314 @default.
- W147809265 cites W2082209278 @default.
- W147809265 cites W2086788410 @default.
- W147809265 cites W2091209489 @default.
- W147809265 cites W2091226635 @default.
- W147809265 cites W2137348095 @default.
- W147809265 cites W2150920000 @default.
- W147809265 cites W2166089818 @default.
- W147809265 cites W2331625330 @default.
- W147809265 cites W2410372681 @default.
- W147809265 cites W2749776293 @default.
- W147809265 cites W4236137448 @default.
- W147809265 cites W4238580586 @default.
- W147809265 cites W4247951076 @default.
- W147809265 doi "https://doi.org/10.1016/s0021-9673(03)00391-1" @default.
- W147809265 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12938887" @default.
- W147809265 hasPublicationYear "2003" @default.
- W147809265 type Work @default.
- W147809265 sameAs 147809265 @default.
- W147809265 citedByCount "159" @default.
- W147809265 countsByYear W1478092652012 @default.
- W147809265 countsByYear W1478092652013 @default.
- W147809265 countsByYear W1478092652014 @default.
- W147809265 countsByYear W1478092652015 @default.
- W147809265 countsByYear W1478092652016 @default.
- W147809265 countsByYear W1478092652017 @default.
- W147809265 countsByYear W1478092652018 @default.
- W147809265 countsByYear W1478092652019 @default.
- W147809265 countsByYear W1478092652020 @default.
- W147809265 countsByYear W1478092652021 @default.
- W147809265 countsByYear W1478092652022 @default.
- W147809265 countsByYear W1478092652023 @default.
- W147809265 crossrefType "journal-article" @default.
- W147809265 hasAuthorship W147809265A5062575590 @default.
- W147809265 hasAuthorship W147809265A5086157711 @default.
- W147809265 hasConcept C111368507 @default.
- W147809265 hasConcept C120665830 @default.
- W147809265 hasConcept C121332964 @default.
- W147809265 hasConcept C127313418 @default.