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- W1479804709 abstract "Konduktometrische Untersuchungen an Lösungen des Na-ε-caprolactams (eines Katalysators der aktivierten anionischen Polmerisation) in der Caprolactamschmelze in Gegenwart von N-Acetyl-ε-caprolactam, Dibenzo-18-crown-6 und Natriumtetraphenylborat werden beschrieben. Anhand der konduktometrischen und kinetischen Untersuchungen wird gezeigt, daß die aktivierte anionische Polymerisation von ε-Caprolactam sowohl an freien Anionen als auch an Ionenpaaren verläuft. Die Möglichkeit der Polymerisation des Monomers nach dem ionischen Koordinationsmechanismus wird betrachtet. Conductometric investigations with solutions of Na-ε-caprolactam (catalyst of the activated anionic polymerization) in the caprolactam melt in the presence of N-acetyl-ε-caprolactam, dibenzo-18-crown-6 and sodium tetraphenyl borate are described. Based on conductometric and kinetic results the activated anionic polymerization of ε-caprolactam is shown to proceed at free anions as well as at ion pairs. The possibility of the polymerization of the monomer by the ionic coordination mechanism is considered." @default.
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- W1479804709 date "1981-01-01" @default.
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- W1479804709 doi "https://doi.org/10.1002/actp.1981.010320108" @default.
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