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• W1480072436 abstract "Methylenebisthiopropionic acid, CH2(S. CH2. CH2. COOH)2, form stable complexes, with cobalt(II), nickel(II) and copper(II), of the type ML.XH2O (M = Metal, L = Ligand, X = 2 for cobalt(II) and nickel(II) and X = 0 for copper(II)). Their structures have been characterised on the basis of elemental analysis, magnetic moment, electronic and i.r. spectral studies. Cobalt(II) and nickel(II) form high-spin octahedral complexes and the copper(II) forms a distorted octahedral complex. I.R. spectra shows that coordination takes place through both sulphur and carboxylate groups of the ligand. Relevant ligand field parameters have been reported for these complexes. The nephelauxetic effect seems to be more effective for cobalt(II) than nickel(II)." @default.
• W1480072436 created "2016-06-24" @default.
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• W1480072436 date "1975-12-01" @default.
• W1480072436 modified "2023-09-24" @default.
• W1480072436 title "Metal complexes of thiopolycarboxylic acid—I" @default.
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• W1480072436 doi "https://doi.org/10.1016/0022-1902(75)80866-9" @default.
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