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- W1480353650 abstract "L'étude du système ternaire obtenu à partir de la phase LiVWO6 par les substitutions V5++ Li+ = W6+ + □ et 2V5+ = W6+ + V4+ a a permis de délimiter à 700°C les domaines d'homogénéité de deux phases, l'une de type brannérite, l'autre de type columbite. Une étude structurale complète montre que les atomes de vanadium et de tungstène sont distribués de manière désordonnée dans les sites cristallographiques, sauf pour une composition voisine de LiV12W32O6, pour laquelle a été mis en évidence un ordre cristallographique. Les auteurs montrent la filiation structurale entre les phases PbO2α, columbite et LiV12W32O6. The study of the ternary system obtained from LiVWO6 phase by the substitutions V5++ Li+ = W6+ + □ and et 2V5+ = W6+ + V4+ has allowed to delimit at 700°C the homogeneity ranges of two phases, one of the brannerite type, the other of the columbite type. A complete structural study shows a disordered distribution for the vanadium and tungsten atoms in the crystallographic sites except for a random composition of LiV12W32O6 where a crystallographic order has been determined. The authors show the structural filiation between the PbO2α, columbite and LiV12W32O6 phases." @default.
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- W1480353650 date "1971-08-01" @default.
- W1480353650 modified "2023-09-24" @default.
- W1480353650 title "Etude cristallographique du systeme ternaire Á 700°C" @default.
- W1480353650 cites W1998693884 @default.
- W1480353650 cites W2012615759 @default.
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- W1480353650 doi "https://doi.org/10.1016/0022-1902(71)80215-4" @default.
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