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- W1480452395 abstract "New cyclometallated compounds of RhIII and IrIII with 2-arylpyridines (1) have been prepared, including chloro-bridged dimers, [M(1)2Cl]2, and mononuclear species containing diethyldithiocarbamate (dtc), [Rh(1)2dtc]. 1H NMR studies have established a trans-nitrogen octahedral structure for all of these compounds. These studies have also strongly suggested that in the planar d8 [Pd(1)dtc] complex there is metal-to-ligand back bonding, whereas in the octahedral d6 [Rh(1)2dtc] no such bonding occurs. Furthermore, in the PdII complex the methyl groups are found to be in non-equivalent sites whereas the methylene protons seem to be in magnetically equivalent sites. The reverse is true for the RhIII complex. These observations are explained by the different structures of the Pd and Rh complexes, and perhaps also by subtle differences in the metal—ligand bonding to both the arylpyridine and the dtc ligands." @default.
- W1480452395 created "2016-06-24" @default.
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- W1480452395 date "1981-07-01" @default.
- W1480452395 modified "2023-09-28" @default.
- W1480452395 title "Cyclometallation" @default.
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- W1480452395 doi "https://doi.org/10.1016/s0022-328x(00)86634-6" @default.
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