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- W1480480788 abstract "Abstract The heat capacity of ammonium hexabromoplatinate (NH4)2PtBr6was measured fromT=6 K toT=320 K by using adiabatic calorimetry. One λ-shaped anomaly was found in the curve for heat capacity against temperature. This λ-shaped transition reaches its maximumCp, m=369.3·RatT=(57.4±0.1) K, with ΔtrsSm°=(2.491±0.028)·Rcharacteristic of an order–disorder transition. From our results, the standard molar entropy ΔT0Sm°{(NH4)2PtBr6, cr}/R=(57.36±0.10), whereT=298.15 K andR=8.31451 J·K−1·mol−1. On the basis of this result, the free energy function Φm°{(NH4)2PtBr6, cr}/R=(33.01±0.06). Smoothed values of the standard thermodynamic quantities for pure (NH4)2PtBr6are tabulated at temperatures up toT=320 K." @default.
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- W1480480788 date "1998-12-01" @default.
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- W1480480788 title "Thermodynamics of ammonium haloplatinates IV. Heat capacity, phase transitions, and thermodynamic properties of (NH4)2PtBr6fromT=6 K toT=320 K" @default.
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- W1480480788 doi "https://doi.org/10.1006/jcht.1998.0430" @default.
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