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• W1480811984 abstract "The dependence of hcrit on the macroscopic contact angle is discussed using measurements of the critical rupture thickness of wetting films on methylated glass surfaces. The rupture thickness increases with increasing contact angles on rather hydrophilic substrates but becomes, however, independent of ΘA on moderately hydrophobic surfaces once ΘA exceeds 45°. A qualitative estimation of the interaction forces reveals that hydrophobic interaction forces are the primary cause of the film rupture. The dimension of the first hole in the film lies in the range of 100 nm, indicating that macroscopic contact angles are not appropriate parameters in this context. A heterogeneous distribution of contact angles on microscopic length scales is demonstrated by means of droplet condensation. Earlier studies postulating a function hcrit=f(Θ) on various hydrophobic surfaces as well as on a wide range of contact angles could not be confirmed. Instead, the heterogeneity of the surface plays a more important role for thin film rupture." @default.
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• W1480811984 date "1999-10-01" @default.
• W1480811984 modified "2023-09-29" @default.
• W1480811984 title "Rupture of thin wetting films on hydrophobic surfaces" @default.
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• W1480811984 doi "https://doi.org/10.1016/s0927-7757(99)00118-1" @default.
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