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- W1481796768 abstract "Reaction of [Li2(Et2O)]Pt(CH2CH2CH2CH2)2 (1) with N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) in diethylether (Et2O) gives [Li(PMDETA)]2Pt(CH2CH2CH2CH2)2 (2). The complex has been characterized by DTA analysis, 1H and 13C NMR spectroscopy and X-ray crystallography. The thermal properties and the structures of 2 and [Li(TMEDA)]2Pt(CH2CH2CH2CH2)2 (3) indicate the significant difference of the influence of PMDETA and N,N,N′,N′-tetramethylethylenediamine (TMEDA) on the platinacyclopentane system. Die Umsetzung von [Li2(Et2O)]Pt-(CH2CH2CH2CH2)2 (1) mit N,N,N′,N″,N″-Pentamethyldiethylentriamin (PMDETA) in Diethylether ergibt [Li(PMDETA)]2Pt-(CH2CH2CH2CH2)2 (2). Der Komplex wurde charakterisiert durch DTA, 1H- und 13C-NMR-Spektroskopie und Röntgenstrukturanalyse. Die thermischen Eigenschaften und die Strukturen von 2 und [Li(TMEDA)]2Pt-(CH2CH2CH2CH2)2 (3) weisen auf den signifikanten Unterschied des Einflusses von PMDETA und N,N,N′,N′-Tetramethylethylendiamin (TMEDA) auf das Platinacyclopentansystem hin." @default.
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- W1481796768 date "1994-05-01" @default.
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- W1481796768 title "Beiträge zur chemie organometallischer metallacyclischer nebengruppenmetallverbindungen" @default.
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- W1481796768 doi "https://doi.org/10.1016/0022-328x(94)88100-6" @default.
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