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- W1483011197 abstract "Abstract A stable derivative of cyclooctatrienyne (1), namely 1,4,7,10-tetramethyl-5,6-didehydrodibenzo-[a,e]cyclooctene (3), has been synthesized and fully characterized. X-Ray crystallographic analyses indicate that 3 adopts a “butterfly” conformation intermediate between those of virtually planar 5,6-didehydrodibenzo-[a,e]cyclooctene (2) and tub-shaped 1,4,7,10-tetramethyldibenzo[a,e]cyclooctene(16). The methyl substituents effectively shield the otherwise rather exposed strained triple bond of 3 and kinetically stabilize it against dimerization and/or air oxidation." @default.
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- W1483011197 date "1986-05-27" @default.
- W1483011197 modified "2023-10-17" @default.
- W1483011197 title "ChemInform Abstract: A Stable Derivative of Cyclooctatrienyne. Synthesis and Crystal Structures of 1,4,7,10-Tetramethyl-5,6-didehydrodibenzo[a,e]cyclooctene and 1,4,7,10-Tetramethyldibenzo[a,e]cyclooctene." @default.
- W1483011197 cites W3119573245 @default.
- W1483011197 doi "https://doi.org/10.1002/chin.198621160" @default.
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