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• W1483147483 abstract "This chapter discusses the modeling of CO2 fluxes in aquatic systems. The instantaneous molecular-scale thermodynamic calculations of CO2 aqueous chemistry are discussed in the chapter. The millimeter scale processes that govern gas transfer kinetics across the air–sea interface, the 100 m scale dynamics of mixing and biogeochemistry in the upper ocean, and the mesoscale eddies and gyre circulation are discussed in detail. On a molecular level, the partitioning of gases between gaseous and aqueous phases is governed by thermodynamics in the form of Henry's law. The sources of nutrients and carbon at the sea surface include (1) seasonal and faster changes in the depth of the mixed layer, (2) large-scale upwelling in equatorial and subpolar oceans, (3) transient uplift of the thermocline in mesoscale eddies, (4) irreversible mixing required to bring subsurface geochemical signatures—such as O2 and 3He—to the sea surface, and (5) nitrogen fixation. These mechanisms have distinct signatures on the tracers O2 and 3He. Mesoscale processes are a crucial part of the geochemical cycles of gases and associated biological tracers in the upper ocean, but models of ocean-gas chemistry at the mesoscale are still working in the diagnostic stage." @default.
• W1483147483 created "2016-06-24" @default.
• W1483147483 creator A5086337448 @default.
• W1483147483 date "1999-01-01" @default.
• W1483147483 modified "2023-09-23" @default.
• W1483147483 title "Modelling carbon dioxide in the ocean: A review" @default.
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• W1483147483 doi "https://doi.org/10.1016/s0167-5117(98)80029-3" @default.
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