Matches in SemOpenAlex for { <https://semopenalex.org/work/W1483442022> ?p ?o ?g. }
Showing items 1 to 59 of
59
with 100 items per page.
- W1483442022 endingPage "4284" @default.
- W1483442022 startingPage "4279" @default.
- W1483442022 abstract "The azide and amide complexes (NBu4)[Ni(N3)('S3')] (2) and (NBu4)[Ni[N(SiMe3)2]('S3')] (4) were found to react with CO, CO2, and SO2 under very mild conditions at temperatures down to -50 degrees C. Depending on the N oxidation state of the nitrogen ligands, addition or partial to complete desoxygenation of the oxides takes place. The reaction between 2 and CO gives (NBU4)[Ni(NCO)('S3')] (3). The reactions between 4 and CO, CO2, and SO2 afford selectively the cyano, isocyanato, and sulfinylimido complexes (NBu4)[Ni(X)('S3')] with X = CN- (5), NCO- (3), and NSO- (6). The silyl groups act as oxygen acceptors. Mechanisms are suggested which have in common the formation of reactive five-coordinate (NBu4)[Ni(L)(L')('S3')] intermediates. In these reactions, highly activated L and L' react with each other. The complexes were characterized by standard methods, and (NBu4)[Ni(CN)('S3')] (5) was also analyzed by X-ray crystallography." @default.
- W1483442022 created "2016-06-24" @default.
- W1483442022 creator A5051317911 @default.
- W1483442022 creator A5070231790 @default.
- W1483442022 creator A5086284568 @default.
- W1483442022 date "2000-12-01" @default.
- W1483442022 modified "2023-10-16" @default.
- W1483442022 doi "https://doi.org/10.1002/1521-3765(20001201)6:23<4279::aid-chem4279>3.0.co;2-s" @default.
- W1483442022 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11140957" @default.
- W1483442022 hasPublicationYear "2000" @default.
- W1483442022 type Work @default.
- W1483442022 sameAs 1483442022 @default.
- W1483442022 citedByCount "18" @default.
- W1483442022 countsByYear W14834420222015 @default.
- W1483442022 countsByYear W14834420222017 @default.
- W1483442022 countsByYear W14834420222018 @default.
- W1483442022 countsByYear W14834420222022 @default.
- W1483442022 crossrefType "journal-article" @default.
- W1483442022 hasAuthorship W1483442022A5051317911 @default.
- W1483442022 hasAuthorship W1483442022A5070231790 @default.
- W1483442022 hasAuthorship W1483442022A5086284568 @default.
- W1483442022 hasConcept C155647269 @default.
- W1483442022 hasConcept C161790260 @default.
- W1483442022 hasConcept C178790620 @default.
- W1483442022 hasConcept C185592680 @default.
- W1483442022 hasConcept C2778439535 @default.
- W1483442022 hasConcept C2778591166 @default.
- W1483442022 hasConcept C2780997848 @default.
- W1483442022 hasConcept C71240020 @default.
- W1483442022 hasConceptScore W1483442022C155647269 @default.
- W1483442022 hasConceptScore W1483442022C161790260 @default.
- W1483442022 hasConceptScore W1483442022C178790620 @default.
- W1483442022 hasConceptScore W1483442022C185592680 @default.
- W1483442022 hasConceptScore W1483442022C2778439535 @default.
- W1483442022 hasConceptScore W1483442022C2778591166 @default.
- W1483442022 hasConceptScore W1483442022C2780997848 @default.
- W1483442022 hasConceptScore W1483442022C71240020 @default.
- W1483442022 hasIssue "23" @default.
- W1483442022 hasLocation W14834420221 @default.
- W1483442022 hasLocation W14834420222 @default.
- W1483442022 hasOpenAccess W1483442022 @default.
- W1483442022 hasPrimaryLocation W14834420221 @default.
- W1483442022 hasRelatedWork W1483442022 @default.
- W1483442022 hasRelatedWork W1985793228 @default.
- W1483442022 hasRelatedWork W2023281720 @default.
- W1483442022 hasRelatedWork W2035205215 @default.
- W1483442022 hasRelatedWork W2060539758 @default.
- W1483442022 hasRelatedWork W2083053336 @default.
- W1483442022 hasRelatedWork W2329867129 @default.
- W1483442022 hasRelatedWork W2341638127 @default.
- W1483442022 hasRelatedWork W2891055625 @default.
- W1483442022 hasRelatedWork W2949825340 @default.
- W1483442022 hasVolume "6" @default.
- W1483442022 isParatext "false" @default.
- W1483442022 isRetracted "false" @default.
- W1483442022 magId "1483442022" @default.
- W1483442022 workType "article" @default.