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- W1483593340 abstract "Supramolecular polymers are macromolecules in which the monomer units are kept together by non-covalent interactions. In a broader sense, the term is also used for selforganized macromolecules of conventional polymers involving non-covalent interactions to determine their material properties (M. Zigon, G. Ambrozic, 2003). It is well known that the physical properties of linear polymers and organic molecules are strongly modified when they contain associating end groups. Supramolecular polymers combine the features of supramolecular species with polymeric properties Self-organizing materials, which include liquid-crystalline polymers, block copolymers, hydrogen-bonded complexes, biological polymers, have great potential for various functional materials. Manipulation of supramolecular nanostructure in self-organizing materials is of critical importance for achieving desired functions and properties in solid state and liquid crystalline state molecular materials (M. Lee, B.K. Cho, et.al. 1999). Although hydrogen bonds between neutral organic molecules are not very strong, they play a very important part in molecular recognition, self-assembling in bio-macromolecules, increasing miscibility in polymers blends, organization in liquid crystals. The directionality and versatility of the hydrogen bonds are the major keys for their implication in supramolecular polymers design. It has been observed that hydrogen bonding in supramolecular polymers is enhanced by liquid crystallinity and phase separation (. L. Brunsveld, B.J.B. Folmer, et.al., 2001). The self-assembly of carboxylic acids as proton donors with pyridyl fragments as proton acceptors is most frequently used in the formation of H-bonded structures [4]. Such supramolecular polymers have been obtained and investigated, especially for liquid crystalline properties [M.Lee, B.K. Cho, et.al. 1999, M. Parra, P. Hidalgo et.al., 2005, H. Han, A.H. Molla et.al., 1995, Y.S. Kang, H. Kim et.al., 2001, M. Parra, P. Hidalgo et. al., 2005; P.K. Bhowmik, X.Wang et. al., 2003, 2, 4-8]. Siloxane-containing benzoic acids and bipyridine also form interesting supramolecular structures, with cubic mesophases (E. Nishikawa, E. T. Samulski, 2000). This paper presents the sensitivity of gases in specially CO2 of the organosiloxane supramolecular polymers. 15" @default.
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- W1483593340 date "2010-04-01" @default.
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- W1483593340 title "Organo-Siloxane Supramolecular Polymers Used in CO2 Detection-Polymer Thin Film" @default.
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- W1483593340 doi "https://doi.org/10.5772/8398" @default.
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