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- W1483673615 abstract "The visible absorption band of iodine adsorbed on zeolite blue shifted with the increase in the electropositivity of the counter cation and the aluminum content in the framework. Since the visible band of iodine in solution has been known to blue shift with the increase in the basicity (donor strength) of the solvent, the blue shift over zeolite was attributed to the increase in the basicity of the zeolite framework, from the consideration of zeolite as a solid solvent. The framework structure, moisture content and the degree of NH3 loss from NH4+-exchanged zeolites also greatly affected the absorption band of iodine. The results established the charge-transfer interaction between the adsorbed iodine and the zeolite oxide surface which allow iodine to be used as a novel molecular probe for the systematic evaluation of the zeolite basicity." @default.
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- W1483673615 date "1997-01-01" @default.
- W1483673615 modified "2023-09-24" @default.
- W1483673615 title "Characterization of zeolite basicity using iodine as a molecular probe" @default.
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- W1483673615 doi "https://doi.org/10.1016/s0167-2991(97)80615-5" @default.
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