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- W1484009951 abstract "The dibenz[c,f]-1,2-oxazepines IId and IIe were obtained as the major products from 9-cyano- and 9-chloroacridine 10-oxides (1d and 1e) by irradiation (⩾300 nm) in benzene, and found to undergo a variety of isomerization reactions under mild conditions in the dark. Existence of the same species (IIa-IIc) in the irradiated solution of acridine 10-oxide (1a) and its methylated derivatives (1b and 1c) was also confirmed by UV spectroscopy as well as by some trapping experiments. The direct isolation of IId and IIe not only constitutes the first synthesis of 1,2-oxazepine derivatives but also gives experimental support to the previously suggested mechanism (Chart 1) for the photolyses of acridine 10-oxides and the related N-oxides." @default.
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- W1484009951 date "1979-01-01" @default.
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- W1484009951 title "Studies on the n-oxides of π-deficient n-heteroaromatics—XXX" @default.
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- W1484009951 doi "https://doi.org/10.1016/0040-4020(79)80053-8" @default.
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