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- W1484998210 abstract "This chapter presents the first successful achievement of the molecular surgery involving the following steps: (1) creation of an opening on the fullerene cage, (2) enlargement of the opening, (3) insertion of some guest species through the enlarged opening, and (4) closure of the opening without losing any of the guest species, to give novel endohedral fullerenes (C60) containing encapsulating helium, dihydrogen, or water. In contrast to the endohedral metallofullerenes, where the electronic properties of carbon cages are significantly altered by electron transfer from the encapsulated metals, such change has not been observed at all in these complexes encapsulating the neutral species. H2@C60 and H2@C70 are very interesting molecular systems in which the H2 molecule is completely isolated by the carbon cage from the outside world surrounding it. The chapter demonstrates the application of some open-cage fullerenes as n-type semiconductor materials in bulk-heterojunction (BHJ) solar cells." @default.
- W1484998210 created "2016-06-24" @default.
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- W1484998210 date "2013-08-16" @default.
- W1484998210 modified "2023-10-08" @default.
- W1484998210 title "Organic Synthesis of Endohedral Fullerenes Encapsulating Helium, Dihydrogen, and Water" @default.
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- W1484998210 doi "https://doi.org/10.1002/9781118354377.ch11" @default.
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