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- W1485103469 abstract "Fluoroacyl complexes of iridium have been prepared by reaction of XeF2 with iridium carbonyl complexes [Ir(CO)3L2]+(L = PMe3, PMe2Ph, PEt2Ph or PEtPh2), [Ir(CO)2Cl(PMe3)2] and [Ir(CO)-(PMe3)4]+. The reaction can be viewed as an unusual type of oxidative addition and this is supported by the need for strongly electron-donating phosphines for reaction to occur. The complex [Ir(CO)2F(COF)-(PEt3)2]+ reacts with SiH3X (X = CN, NCS or NCO) to give acyl complexes [Ir(CO)2F(COX)(PEt3)2]+ and with BF3 to give [Ir(CO)3F(PEt3)2]2+. This dication reacts further with PMe3 to give an acyl product with PMe3 bound to a carbonyl ligand. The complex [Ir(CO)3(PPh3)2]+ reacts with XeF2+ BF3 to give [Ir(CO)3F(PPh3)2]2+. Products were characterised using 19F, 31P and 13C NMR spectroscopy." @default.
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- W1485103469 date "1993-04-07" @default.
- W1485103469 modified "2023-09-25" @default.
- W1485103469 title "FORMATION OF IRIDIUM FLUOROACYL COMPLEXES BY REACTION OF IRIDIUM CARBONYLS WITH XEF2 AND REACTIONS OF THESE TO GENERATE UNUSUAL ACYL COMPLEXES" @default.
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