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- W1485205619 abstract "Abstract The thermodynamic formation constant of silver chloride complexes in mixed aqueous-ethanol solvents are determined by the solubility measurements as a function of the chloride concentration. The formation constant for a complex species MX n in the mixed solvent (denoted with the subscript s ) with respect to pure water( w ) has the relation: log w β n − log s β n = log m γMX − log m γ Mm γx n , which shows the difference being mainly caused by the specific ion-solvent interaction of individual ions in the solution and can be interpreted by the change in the “chemical energy of solvation” for ions. With the aid of the medium effects for the chloride ion ( m γ Cl ) in the system, which are available in the literature, the medium effects for the silver ion and the silver chloride complex species are calculated and the preferential solvation of the silver and the chloride ion is further interpreted." @default.
- W1485205619 created "2016-06-24" @default.
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- W1485205619 date "1977-06-07" @default.
- W1485205619 modified "2023-09-27" @default.
- W1485205619 title "ChemInform Abstract: PREFERENTIAL SOLVATION OF SINGLE IONS. I. STUDIES OF SILVER AND SILVER CHLORIDE IONS BY THE DETERMINATION OF SOLUBILITY PRODUCTS AND FORMATION CONSTANTS IN MIXED AQUEOUS-ETHANOL MEDIA" @default.
- W1485205619 cites W4250577389 @default.
- W1485205619 doi "https://doi.org/10.1002/chin.197723015" @default.
- W1485205619 hasPublicationYear "1977" @default.
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