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- W1485208604 abstract "Dye-sensitized and nonsensitized photooxygenation of 3,5-di-t-butylpyrocatechol (1), 2,5-di-t-butylhydroquinone (14), their monomethyl ethers 4 and 20, and dimethyl ethers 5 and 21 has been investigated. In methanol, 1 and 4 undergo oxidative ring cleavage to give a lactonic acid 2 and/or its methyl ester 3. This represents a model for the enzymatic cleavage of phenolic rings. Under similar conditions 14 and 20 give 2,5-di-t-butylbenzoquinone 15 and further transformation products. Mechanisms involving initial formation of a corresponding phenoxy radical are proposed. The dimethyl ethers 5 and 20 do not react under these conditions. Other related reactions are described." @default.
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- W1485208604 date "1972-01-01" @default.
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- W1485208604 title "Photoinduced reactions—LVII" @default.
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- W1485208604 doi "https://doi.org/10.1016/s0040-4020(01)88931-6" @default.
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