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- W1485385810 abstract "Abstract The C-signals for the C12-chain in η3,η2,η2-dodeca-2(E),6(E),10(Z)-triene-1-yl-nickel(II) hexafluorophosphate, a catalyst for the 1,4-cis-polymerization of butadiene, could be assigned by use of 2D-13C/1H and 1H/1H NMR spectroscopy (HMQC and TOCSY). Furthermore, by use of high resolution 1H NMR spectroscopy a large number of vicinal coupling constants 3J of the [Ni(C12H19)]+-cation could be determined in the C12-allylnickel(II) complexes [Ni(C12H19)]X (X = PF6, B(C6H 3(CF3)2)4, B(C6F5)3F). They were correlated with the torsion angles in the C12-chain by using the method of Karplus. The angles thus determined agreed well with those determined by X-ray structure analysis for the hexafluorophosphate. Thus the same conformation can be assumed for the [Ni(C12H19)]+-cation in the solution and in the crystal lattice. The mechanistic consequences for the catalysis of 1,4-cis-polymerization of butadiene are also discussed." @default.
- W1485385810 created "2016-06-24" @default.
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- W1485385810 date "1993-08-01" @default.
- W1485385810 modified "2023-10-14" @default.
- W1485385810 title "Komplexkatalyse" @default.
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- W1485385810 doi "https://doi.org/10.1016/0022-328x(93)83327-r" @default.
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