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- W1485687586 abstract "Abstract Under certain simplifying assumptions a simple mathematical model can be used to describe pulse broadening due to non-equilibrium chromatography. Neglecting diffusional effects and assuming linear rates of adsorption and desorption a system of partial differential equations was obtained and solved analytically. The solution, which is valid for any input pulse function, has been used to predict the effect of the rate parameters on the shape and position of the output pulse. Therefore, experimental curves can be compared with the model predictions in order to obtain the rate parameters. The chemisorption rates of hydrogen on a nickel catalyst were measured in the −30 to 25°C temperature range. The results are in good agreement with those obtained by the moments' equations and the plate height theory." @default.
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- W1485687586 date "1980-08-01" @default.
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- W1485687586 title "Gas chromatographic determination of adsorption-desorption rates" @default.
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