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• W1486156246 abstract "Rh(I) complexes of S-triazines and azobenzene were found to be very efficient towards the catalytic hydrogenation of alkenes, alkynes at normal pressure, and at room temperature. Reduction of aromatic nitrocompounds, benzaldehyde, and benzil were observed in appreciable amounts only at high pressure and at high temperature. No diminished catalytic activity was observed even after 6–8 repeated catalytic runs. Profound effect was observed on the rate of reduction in presence of extra ligand without affecting the nature of yield, both under normal and high pressure conditions. Kinetics was studied. Mechanism has been proposed and rate equation has been derived." @default.
• W1486156246 created "2016-06-24" @default.
• W1486156246 creator A5020638457 @default.
• W1486156246 creator A5074614193 @default.
• W1486156246 date "2010-11-30" @default.
• W1486156246 modified "2023-10-16" @default.
• W1486156246 title "Dihydrogen Reduction of Nitroarmatics, Alkenes, Alkynes, Benzaldehyde, and Benzil by Newly Synthesized Rh(I) Complexes in Homogeneous Phase" @default.
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• W1486156246 doi "https://doi.org/10.1080/15533174.2010.522539" @default.
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