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- W1487017036 abstract "This chapter presents a one-dimensional model for viscoelastic diffusion in polymers. Flow occurs in a mixture with relative motion between components, driven by a combination of thermodynamic and mechanical forces. The simplest case involves only two components with no applied mechanical tractions; the relative motion is mutual diffusion, generally resulting in flow of each component dominated by dilation. This situation is discussed for one-dimensional motions in the case of a binary mixture with one viscoelastic component and the other an ordinary viscous fluid. A quantitative understanding of mutual diffusion in concentrated polymer/viscousfluid mixtures is of great practical importance to understand and control a number of polymer processing operations and end-use applications. Experimental studies indicate that unsteady, one-dimensional diffusion in concentrated polymer/viscous-fluid mixtures ranges from ordinary Fickian behavior to strongly non-Fickian, depending on some conditions. A one-dimensional nonlinear model for viscoelastic diffusion in concentrated polymer-fluid mixtures is constructed by an ad-hoc generalization of the linear response model." @default.
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- W1487017036 date "1999-01-01" @default.
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- W1487017036 title "A one-dimensional model for viscoelastic diffusion in polymers" @default.
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- W1487017036 doi "https://doi.org/10.1016/s0169-3107(99)80023-9" @default.
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