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• W1487152142 abstract "The phase diagram of the ternary CoO-V2O5-MoO3 system and in particular its T-CoV2O6-MoO3 slice have been determined with DTA and X-ray phase analysis. CoV2O6 crystallizes in two modifications: a low-temperature γ-form of unknown structure and a high-temperature α-form of brannerite-type structure. The transition temperature is 660-665°C. The γ ⇌ α transformations are very slow and the α-polymorph may be easily frozen. On doping with MoO3, a solid solution is formed that is described by the formula Co1−x∅xV2−2xMo2xO6. Above x = 0.02 the α-type structure is stabilized. The xmax equals 0.22 at the eutectic temperature of 620°C and 0.20 at room temperature. Other features of the phase diagram, including its division into the natural subdiagrams and three ternary eutectics, are described in detail. X-Ray data are listed for α-CoV2O6 and for the solid solution having x = 0.20. On doping with MoO3 the monoclinic lattice dilates primarily in the direction of the b-axis." @default.
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• W1487152142 date "1985-01-01" @default.
• W1487152142 modified "2023-09-26" @default.
• W1487152142 title "Defect structures in the brannerite-type vanadates" @default.
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• W1487152142 doi "https://doi.org/10.1016/0022-4596(85)90255-5" @default.
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