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- W1487231489 abstract "The tide compound was synthesised in the optically active form in seven steps from (4 R ,6 R )-actinol in 34% overall yield. The relative configuration within the C 15 -key intermediate acetylenic triol, 2- E -5-((1S,4 R ;,6 R )-1,4-dihydroxy-2,2,6-trimethylcyclohexyl)-3-methyl-2- penten-4-yn-1-ol, was determined by X-ray crystallographic analysis. The title compound A was synthesized in the optically active form in seven steps via B from (4 R ,6 R )-actinol ( C ) in 34% overall yield. The relative configuration of the C 15 -key intermediate acetylenic triol, 2- E -5-((1 S ,4 R ,6 R )-1,4-dihydroxy-2,2,6-trimethylcyclohexyl)-3-methyl-2-penten-4-yn-l-ol ( B ), was determined by X-ray crystallographic analysis." @default.
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- W1487231489 date "1994-07-01" @default.
- W1487231489 modified "2023-10-16" @default.
- W1487231489 title "Total synthesis of acetylenic carotenoids" @default.
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- W1487231489 doi "https://doi.org/10.1016/0957-4166(94)80179-7" @default.
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