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- W1487238049 abstract "The synthesis of poly(3-n-alkyl-4-oxybenzoate)s (PAOB-n) with n = 3–18 is reported. The sufficient solubility of these comb-like polymers with stiff-chain backbones allows the determination of the Kuhn length (100–200 Å). The unit cells could be determined for PAOB-n with n = 3 and 5. All PAOB-n form thermotropic mesophases. For n = 3 a nematic phase is found. For n = 5 there is a transition from a smectic-like, layered mesophase to a nematic mesophase. PAOB-n with n ⩾ 6 solely form layered mesophases. Except for n = 3, all PAOB-n exhibit a transition to the isotropic state. The transition temperature is lowered monotomically with increasing n." @default.
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- W1487238049 date "1991-01-01" @default.
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- W1487238049 title "Rigid rod polymers with flexible side chains" @default.
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- W1487238049 doi "https://doi.org/10.1016/0032-3861(91)90178-l" @default.
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