Matches in SemOpenAlex for { <https://semopenalex.org/work/W1487488775> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W1487488775 abstract "The first application of time-resolved fast X-ray photoelectron spectroscopy as a chemically specific, quantitative probe for surface catalysed organic synthesis is described. The trimerisation of ethyne to benzene over a catalytically active Pd(111) surface has been followed in situ by C 1s core-level XPS. Ethyne reacts to form flat-lying (η6) benzene above ≈150 K with a low activation barrier of≈5±1 kJ mol−1. At 280 K a tilted (η1) benzene moeity is formed on the surface, some of which desorbs, the remainder interconverting to flat-lying benzene above 330 K. Unreacted ethyne is not present above 330 K. Flat-lying benzene begins desorbing≈500 K, in competition with C-H bond cleavage to form a tilted (η1 or η2) phenyl species. The latter may disproportionate yielding gaseous benzene and carbon." @default.
- W1487488775 created "2016-06-24" @default.
- W1487488775 creator A5020098885 @default.
- W1487488775 creator A5038843370 @default.
- W1487488775 creator A5060198588 @default.
- W1487488775 date "2000-01-01" @default.
- W1487488775 modified "2023-09-27" @default.
- W1487488775 title "In situ observation of a surface catalysed chemical reaction by fast X-ray photoelectron spectroscopy" @default.
- W1487488775 cites W1966174694 @default.
- W1487488775 cites W2006978352 @default.
- W1487488775 cites W2015094275 @default.
- W1487488775 cites W2016159436 @default.
- W1487488775 cites W2026413388 @default.
- W1487488775 cites W2046503671 @default.
- W1487488775 cites W2046903578 @default.
- W1487488775 cites W2063857277 @default.
- W1487488775 cites W2081957072 @default.
- W1487488775 cites W2082129133 @default.
- W1487488775 cites W2138713767 @default.
- W1487488775 cites W2949678660 @default.
- W1487488775 cites W2952256720 @default.
- W1487488775 doi "https://doi.org/10.1016/s0167-2991(00)80497-8" @default.
- W1487488775 hasPublicationYear "2000" @default.
- W1487488775 type Work @default.
- W1487488775 sameAs 1487488775 @default.
- W1487488775 citedByCount "0" @default.
- W1487488775 crossrefType "book-chapter" @default.
- W1487488775 hasAuthorship W1487488775A5020098885 @default.
- W1487488775 hasAuthorship W1487488775A5038843370 @default.
- W1487488775 hasAuthorship W1487488775A5060198588 @default.
- W1487488775 hasConcept C104779481 @default.
- W1487488775 hasConcept C113196181 @default.
- W1487488775 hasConcept C121332964 @default.
- W1487488775 hasConcept C140205800 @default.
- W1487488775 hasConcept C159985019 @default.
- W1487488775 hasConcept C161790260 @default.
- W1487488775 hasConcept C175156509 @default.
- W1487488775 hasConcept C175708663 @default.
- W1487488775 hasConcept C178790620 @default.
- W1487488775 hasConcept C185592680 @default.
- W1487488775 hasConcept C192562407 @default.
- W1487488775 hasConcept C2777691172 @default.
- W1487488775 hasConcept C2777822432 @default.
- W1487488775 hasConcept C32891209 @default.
- W1487488775 hasConcept C43369102 @default.
- W1487488775 hasConcept C46141821 @default.
- W1487488775 hasConcept C62520636 @default.
- W1487488775 hasConcept C75473681 @default.
- W1487488775 hasConcept C8010536 @default.
- W1487488775 hasConceptScore W1487488775C104779481 @default.
- W1487488775 hasConceptScore W1487488775C113196181 @default.
- W1487488775 hasConceptScore W1487488775C121332964 @default.
- W1487488775 hasConceptScore W1487488775C140205800 @default.
- W1487488775 hasConceptScore W1487488775C159985019 @default.
- W1487488775 hasConceptScore W1487488775C161790260 @default.
- W1487488775 hasConceptScore W1487488775C175156509 @default.
- W1487488775 hasConceptScore W1487488775C175708663 @default.
- W1487488775 hasConceptScore W1487488775C178790620 @default.
- W1487488775 hasConceptScore W1487488775C185592680 @default.
- W1487488775 hasConceptScore W1487488775C192562407 @default.
- W1487488775 hasConceptScore W1487488775C2777691172 @default.
- W1487488775 hasConceptScore W1487488775C2777822432 @default.
- W1487488775 hasConceptScore W1487488775C32891209 @default.
- W1487488775 hasConceptScore W1487488775C43369102 @default.
- W1487488775 hasConceptScore W1487488775C46141821 @default.
- W1487488775 hasConceptScore W1487488775C62520636 @default.
- W1487488775 hasConceptScore W1487488775C75473681 @default.
- W1487488775 hasConceptScore W1487488775C8010536 @default.
- W1487488775 hasLocation W14874887751 @default.
- W1487488775 hasOpenAccess W1487488775 @default.
- W1487488775 hasPrimaryLocation W14874887751 @default.
- W1487488775 hasRelatedWork W1982849289 @default.
- W1487488775 hasRelatedWork W1997587374 @default.
- W1487488775 hasRelatedWork W2000935290 @default.
- W1487488775 hasRelatedWork W2013065711 @default.
- W1487488775 hasRelatedWork W2015094275 @default.
- W1487488775 hasRelatedWork W2036916556 @default.
- W1487488775 hasRelatedWork W2045386314 @default.
- W1487488775 hasRelatedWork W2059975427 @default.
- W1487488775 hasRelatedWork W2064067498 @default.
- W1487488775 hasRelatedWork W2068332626 @default.
- W1487488775 hasRelatedWork W2072691853 @default.
- W1487488775 hasRelatedWork W2076398359 @default.
- W1487488775 hasRelatedWork W2080060531 @default.
- W1487488775 hasRelatedWork W2138713767 @default.
- W1487488775 hasRelatedWork W2186951017 @default.
- W1487488775 hasRelatedWork W2270807986 @default.
- W1487488775 hasRelatedWork W2331980414 @default.
- W1487488775 hasRelatedWork W2517969618 @default.
- W1487488775 hasRelatedWork W2951226182 @default.
- W1487488775 hasRelatedWork W3036783547 @default.
- W1487488775 isParatext "false" @default.
- W1487488775 isRetracted "false" @default.
- W1487488775 magId "1487488775" @default.
- W1487488775 workType "book-chapter" @default.