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- W1488013849 abstract "Abstract Carefully purified starting materials and precisely controlled stoichiometries guarantee high yield “one pot synthesis” of the novel volatile organogalliocobalt complexes 2–7 . These compounds are stabilized by intramolecular adduct formation at the gallium center. Synthesized compounds are identified by 1 H, 13 C, 31 P-NMR, infrared ν(CO) and MS data. A single crystal X-ray analysis of {μ-[3-(diethylamino)propyl]gallio}[bis(tetracarbonylcobalt)] reveals cobalt—gallium bond distances averaging to 254.3 pm. Thermal decarbonylation of 2–4 in the presence of phosphines, e.g. P(C 6 H 5 ) 3 , yields quantitatively the trans -phosphine substituted complexes 5–7 . In polar solvents those latter compounds exhibit a significantly weakened tendency towards heterolytic dissociation of the metal—metal bond. This behavior reflects a strengthened cobalt—gallium interaction, as it is also indicated by mass spectroscopy." @default.
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- W1488013849 date "1992-05-01" @default.
- W1488013849 modified "2023-10-18" @default.
- W1488013849 title "Organoerdmetallkomplexe von d-block-elementen" @default.
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- W1488013849 doi "https://doi.org/10.1016/0022-328x(92)83179-l" @default.
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