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- W1488103687 abstract "A fluorinated analog of the 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) ligand was synthesized with OCF3-substitution of the aryl groups in BINAP skeleton (p-OCF3–BINAP). Ruthenium complexes of both BINAP (Ru–BINAP) and (p-OCF3)–BINAP (Ru–[(p-OCF3)–BINAP]) were also synthesized and investigated as catalysts for hydrogenation of tiglic acid in methanol. Typically, Ru–[(p-OCF3)–BINAP] had lower activity but had higher enantioselectivity at high hydrogen pressures than Ru–BINAP at the same condition. The effect of OCF3 groups on the catalytic properties was discussed on the basis of NMR spectra and kinetic data. Ru–[(p-OCF3)–BINAP] was found to have sufficiently high solubility in dense CO2 for homogeneous catalytic reactions and was investigated for hydrogenation of tiglic acid in CO2. The results showed that CO2 had a great influence on both activity and enantioselectivity. Addition of methanol to CO2 was found to increase the enantioselectivity." @default.
- W1488103687 created "2016-06-24" @default.
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- W1488103687 date "2004-03-15" @default.
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- W1488103687 title "Enantioselective hydrogenation of tiglic acid in methanol and in dense carbon dioxide catalyzed by a ruthenium–BINAP complex substituted with OCF3 groups" @default.
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- W1488103687 doi "https://doi.org/10.1016/j.molcata.2003.10.016" @default.
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