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- W1488308693 abstract "Synthesis of complex oxides by the decomposition of precursor compounds has been known for some time. In general, alkoxides and carboxylates are the precursors employed in the synthesis of metal oxides. Chandler reviewed organometallic precursors employed in the synthesis of some perovskite oxides. It would be instructive to examine a few of the reactions involved in the synthesis of oxides from precursor compounds. This chapter first examines the mode of formation of BaTiO3 from the decomposition of barium titanyloxalate, which is best represented as Ba2Ti2(O)2(C2O4)4. Carbonate solid solutions are ideal precursors for the synthesis of monoxide solid solutions of rock salt structure. Besides monoxide solid solutions, a number of ternary and quaternary oxides of novel structures can be prepared by decomposing carbonate precursors. Metal thiolates, thiocarbonates and dithiocarbonates are good precursors for sulfides. Organometallic precursors are used in the synthesis of a variety of ceramics and superconducting cuprates." @default.
- W1488308693 created "2016-06-24" @default.
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- W1488308693 date "2015-02-20" @default.
- W1488308693 modified "2023-10-17" @default.
- W1488308693 title "Decomposition of Precursor Compounds" @default.
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- W1488308693 doi "https://doi.org/10.1002/9781118892671.ch4" @default.
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