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- W1488407831 abstract "The new oxy-chloro-sulfide (Mn{sub 1-x}Pb{sub x})Pb{sub 10+y}Sb{sub 12-y}S{sub 26-y}Cl{sub 4+y}O (x element of [0.2-0.3]; y element of [0.3-1.6]) was synthesized by dry way at 500-600 deg. C. A single crystal {approx}Mn{sub 0.7}Pb{sub 11.0}Sb{sub 11.3}S{sub 25.3}Cl{sub 4.7}O indicates a monoclinic symmetry, space group C2/m, with a = 37.480(8), b 4.1178(8), c = 18.167(4) A, {beta} = 106.37(3){sup o}, V = 2690.2(9) A{sup 3}, Z = 2. Its crystal structure was determined by X-ray single crystal diffraction, with a final R = 5.11%. Modular analysis of the crystal structure reveals a 'waffle' architecture, where complex rods with lozenge section delimitate an internal channel filled by a single chain of (Mn{sub 0.7}Pb{sub 0.3})Cl{sub 6} octahedra connected by opposite edges. Minimal inter-chain distances are close to 18 A. The rod wall, two-atom thick, presents, in alternation with S atoms, Pb or (Pb,Sb) cations with prismatic coordination in the internal atom layer, while the external atom layer is constituted exclusively by Sb cations with dissymmetric square pyramidal coordination. A (Pb,Sb){sub 2}S{sub 2} fragment connects two successive rods along (2 0 1) to form a waffle-type palissadic layer. The unique O position, half filled, presents the same environment than the isolated O positions in the oxy-sulfidemore » Pb{sub 14}Sb{sub 30}S{sub 54}O{sub 5}, or oxy-chloro-sulfides Pb{sub 18}Sb{sub 20}S{sub 46}Cl{sub 2}O and (Cu,Ag){sub 2}Pb{sub 21}Sb{sub 23}S{sub 55}ClO. This compound belongs to a pseudo-homologous series of chalcogenides with waffle structure, ordered according to the size of their lozenge shape channel. Such a complex senary compound of the oxy-chloro-sulfide type illustrates the structural competition between three cations, on one hand, and, on the other hand, three anions. This compound is of special interest regarding the 1D distribution of magnetic Mn{sup 2+} atoms at the {approx}2 nm scale. - Graphical abstract: Projection of the crystal structure of (Mn{sub 1-x}Pb{sub x})Pb{sub 10+y}Sb{sub 12-y}S{sub 26-y}Cl{sub 4+y}O restricted to two adjacent rods, showing the minimum distance between (Mn, Pb)Cl{sub 4} single chains.« less" @default.
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- W1488407831 date "2007-08-01" @default.
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- W1488407831 title "(Mn1−xPbx)Pb10+ySb12−yS26−yCl4+yO, a new oxy-chloro-sulfide with ∼2nm-spaced (Mn,Pb)Cl4 single chains within a waffle-type crystal structure" @default.
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- W1488407831 cites W1987384929 @default.
- W1488407831 cites W1993902772 @default.
- W1488407831 cites W1996680683 @default.
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- W1488407831 cites W2039849324 @default.
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- W1488407831 doi "https://doi.org/10.1016/j.jssc.2007.05.012" @default.
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