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- W1488455408 abstract "Hexadecafluorophthalocyanine (F16Pc) complexes of Ru(II) which were prepared bythe reaction of tetrafluorophthalonitrile and Ru3(CO)12, have been encapsulated in the supercages of zeolites NaX. The X type zeolites were synthesized around the RuF16Pc complexes. The zeolites modified with the metal complexes were characterized by XRD, FT-IR and UV-Vis spectroscopy as well as elemental analysis. The oxidation of cyclohexane using t-butylhydroperoxide was catalyzed by the intrazeolite RuF16Pc complexes. Complete conversion to cyclohexanone and cyclohexanol was achieved with nearly 3000 turnovers per day. These ship-in-a-bottle RuF16Pc complexes show no signs of deactivation in contrast to the iron analogs, regardless of how the peroxide is administered during the reaction." @default.
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- W1488455408 date "1995-01-01" @default.
- W1488455408 modified "2023-10-11" @default.
- W1488455408 title "Cyclohexane oxidation catalyzed by zeolite encapsulatedruthenium perfluorophthalocyanines" @default.
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- W1488455408 doi "https://doi.org/10.1016/s0167-2991(06)81288-7" @default.
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